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What Is Potassium Tetrachloroplatinate(II)? Properties, Applications and Buying Guide

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Potassium tetrachloroplatinate(II) is a platinum coordination compound used as a starting material in chemical synthesis, platinum-based material research, catalysis, electroplating, and other specialized applications.

Also known as dipotassium tetrachloroplatinate, it contains platinum in the +2 oxidation state and has the molecular formula K₂PtCl₄. Its CAS number is 10025-99-7, and its molecular weight is approximately 415.1 g/mol.

For buyers, understanding its chemical identity, physical properties, application range, purity requirements, documentation, and packaging can help when comparing suppliers and requesting quotations.

Quick Facts About Potassium Tetrachloroplatinate (II)

PropertyInformation
Chemical NamePotassium tetrachloroplatinate(II)
CAS No.10025-99-7
Molecular FormulaK₂PtCl₄
Molecular Weight415.1 g/mol
Platinum Oxidation State+2
AppearanceRed to ruby-red solid
SolubilitySoluble in water
Common SynonymsDipotassium tetrachloroplatinate, potassium chloroplatinite
Main UsesChemical synthesis, platinum materials research, catalysis, electroplating

What Is Potassium Tetrachloroplatinate(II)?

Potassium tetrachloroplatinate(II) is an inorganic platinum compound consisting of potassium ions and the tetrachloroplatinate(II) complex. In simple terms, it provides a convenient source of Pt(II) for chemical reactions and material preparation.

The compound is commonly represented as K₂[PtCl₄]. The platinum center is coordinated by four chloride ligands, forming the square-planar tetrachloroplatinate(II) complex.

This chemical structure makes the compound useful as a starting material for preparing other platinum-containing compounds and functional materials.

For chemical buyers, the CAS number 10025-99-7 is particularly important because it helps distinguish this material from other platinum salts and related platinum complexes.

Potassium Tetrachloroplatinate(II) Properties

1. Chemical Formula and Molecular Weight

The molecular formula of potassium tetrachloroplatinate(II) is:K₂PtCl₄

Its molecular weight is approximately:415.1 g/mol

PubChem lists 415.1 g/mol as the molecular weight for the compound with CAS 10025-99-7.

For procurement, these basic identifiers should be checked against the supplier’s specification sheet and Certificate of Analysis (COA).

2. Appearance

Potassium tetrachloroplatinate(II) is generally described as a red or ruby-red solid. Commercial products may be supplied as a powder or crystalline material depending on the grade and supplier.

Appearance can be useful as a quick incoming inspection point, but it should not replace analytical testing when purity or trace-metal specifications are important.

3. Water Solubility

The compound is reported to be soluble in water.

This property is relevant when potassium tetrachloroplatinate(II) is used in aqueous chemical preparation or as a precursor in solution-based synthesis.

However, actual solubility behavior can depend on concentration, temperature, solution composition, and handling conditions. Buyers should refer to the applicable technical documentation for their intended process.

4. Platinum Content

Because potassium tetrachloroplatinate(II) contains platinum, its platinum content is an important consideration for material buyers.

For example, one commercial high-purity grade lists Pt ≥46.2% on its specification page.

The exact assay and impurity limits can vary between grades, so buyers should compare the actual COA and specification rather than relying only on the chemical name.

Potassium Tetrachloroplatinate(II) Applications

1. Platinum Compound Synthesis

One of its important roles is as a starting material for preparing other platinum-containing compounds.

Because it provides Pt(II) in a defined coordination environment, it can participate in ligand-exchange and related synthetic reactions.

This makes potassium tetrachloroplatinate(II) useful in coordination chemistry and platinum complex research.

2. Platinum Nanoparticle Synthesis

Potassium tetrachloroplatinate(II) can also serve as a platinum precursor in the preparation of platinum nanoparticles and related nanostructured materials.

Commercial technical information describes its use as a precursor for platinum nanoparticles and mesoporous platinum nanospheres.

The ability to introduce platinum into a controlled chemical system makes Pt(II) salts useful in materials research involving particle size, morphology, surface properties, and catalytic performance.

3. Catalysis Research

Platinum is widely studied for catalytic applications, and potassium tetrachloroplatinate(II) can act as a precursor for preparing platinum-containing catalysts.

Research and commercial application information includes its use in catalyst preparation and selective oxidation studies.

For researchers, the value of the material is often not the salt itself as the final catalyst, but its role as a controlled platinum source during catalyst synthesis.

4. Electroplating and Platinum Materials

Potassium tetrachloroplatinate(II) is also associated with electroplating and platinum material preparation. Commercial product information lists electroplating among its applications.

The actual suitability for a particular plating process depends on the formulation, operating conditions, purity requirements, and process specifications.

5. Advanced Materials Research

Platinum compounds are used in research involving:

  • Nanomaterials
  • Electrocatalysts
  • Fuel-cell materials
  • Platinum alloys
  • Functional coordination compounds
  • Optical and electronic materials

Potassium tetrachloroplatinate(II) has been reported as a starting material in several of these research areas.

For this reason, the compound can be relevant to both academic research and industrial R&D programs.

Why Does Purity Matter When Buying Potassium Tetrachloroplatinate(II)?

Purity is one of the first factors buyers should evaluate.

For platinum-containing materials, trace impurities can affect:

  • Reaction performance
  • Catalyst preparation
  • Nanoparticle formation
  • Electrochemical behavior
  • Final material composition
  • Reproducibility between batches

Commercial grades can differ considerably in purity and impurity limits. For example, Sigma-Aldrich lists grades ranging from 98% to high-purity trace-metal specifications, including a 99.99% trace-metal grade.

Therefore, buyers should not compare suppliers based on price alone.

Instead, compare:

Purity + impurity profile + documentation + packaging + batch consistency + supply capability

Potassium Tetrachloroplatinate(II) Buying Guide

If you are sourcing potassium tetrachloroplatinate(II) CAS 10025-99-7, the following points are worth confirming before placing an order.

1. Confirm the CAS Number

The first step is to confirm:

CAS No. 10025-99-7

This helps avoid confusion with other platinum salts and related compounds.

PubChem, Sigma-Aldrich and Fisher Scientific all identify CAS 10025-99-7 as potassium tetrachloroplatinate(II).

2. Confirm the Required Purity

Different applications require different purity levels.

For laboratory synthesis, standard reagent-grade material may be sufficient.

For:

  • catalyst preparation
  • nanoparticle synthesis
  • electrochemical research
  • advanced materials
  • trace-metal-sensitive reactions

a higher-purity grade may be required.

Always specify your required purity before requesting a quotation.

3. Request a COA

A Certificate of Analysis (COA) is useful for checking the actual batch specification.

Depending on the supplier and product grade, a COA may include:

  • Assay
  • Platinum content
  • Appearance
  • Moisture or related parameters
  • Trace metal impurities
  • Batch number
  • Testing date

Do not assume that two products with the same CAS number have identical specifications.

4. Ask About Packaging

Packaging should match the product’s value, quantity, transportation requirements, and intended use.

For small laboratory quantities, smaller sealed containers may be suitable.

For larger orders, buyers should discuss:

  • Net weight
  • Inner packaging
  • Outer packaging
  • Labeling
  • Batch identification
  • Transportation requirements

The packaging should also protect the material from contamination and inappropriate handling.

5. Confirm Documentation

Before purchasing, it is useful to ask which documents are available.

Depending on the supplier and destination, these may include:

  • COA
  • SDS
  • Product specification
  • Certificate of Origin
  • Packing information

For international procurement, documentation can be just as important as the quoted price.

What Should You Ask a Potassium Tetrachloroplatinate(II) Supplier?

A simple supplier inquiry can include:

  • Product: Potassium Tetrachloroplatinate(II)
  • CAS: 10025-99-7
  • Required purity: [your specification]
  • Quantity: [your quantity]
  • Packaging: [your requirement]
  • Destination: [country/port]
  • Required documents: COA / SDS / other documents

Providing these details allows suppliers to check the product specification, availability, packaging and shipping requirements more efficiently.

Safety and Handling Considerations

Potassium tetrachloroplatinate(II) should be handled according to the applicable SDS and local workplace requirements.

Current supplier SDS information classifies the material as hazardous and includes acute oral toxicity, skin irritation, serious eye damage, skin sensitization and respiratory sensitization classifications.

Appropriate laboratory controls may include suitable gloves, protective clothing and eye/face protection, together with measures to avoid breathing dust and to maintain adequate ventilation.

Important: The exact handling requirements should always be based on the SDS for the specific product and grade being purchased.

How to Choose a Reliable Potassium Tetrachloroplatinate(II) Supplier

Price is important, but it should not be the only factor when sourcing a platinum compound.

A practical supplier evaluation should include:

Product Identity

Does the supplier clearly provide:

  • Product name
  • CAS number
  • Molecular formula
  • Grade
  • Purity

Quality Documentation

Can the supplier provide relevant:

  • COA
  • SDS
  • Specification
  • Batch information

Supply Capability

Can the supplier support your required:

  • Quantity
  • Packaging
  • Delivery schedule
  • Repeat orders

Communication

Can the supplier clearly answer questions about specifications, documentation and shipment?

For international B2B purchasing, these factors can help reduce misunderstandings before an order is placed.

Frequently Asked Questions

The CAS number is 10025-99-7. It is also known as dipotassium tetrachloroplatinate and potassium chloroplatinite.

Its molecular formula is K₂PtCl₄, with a molecular weight of approximately 415.1 g/mol.

It is used as a platinum precursor in chemical synthesis, platinum nanoparticle and advanced-material preparation, catalysis research and some electroplating applications.

Yes. PubChem describes potassium tetrachloroplatinate(II) as soluble in water.

Confirm the CAS number, purity, grade, impurity limits, COA, SDS, packaging, quantity and delivery requirements before placing an order.

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