Zhishang Bio Technology|Supplier of pharmaceutical intermediates, pesticide intermediates and cosmetics raw materials

PRODUCT

Benzidine

Zhishang Bio Benzidine CAS 92-87-5

CAS:92-87-5 | C12H12N2 |MW:184.24 | EINECS NO:202-199-1

Payment: L/C,T/T,D/P,Paypal,Money Gram,Western Union

Incoterm: FOB,CFR,CIF,EXW,FCA,CPT,CIP

Transporta: Ocean, Land,Air, DHL,TNT

Port: Shanghai Port, Qingdao Port

Description

Benzidine is a powdery white or light-red crystalline powder when it’s at room temperature. It is alkaline and has a low solubility with water. However, it can be dissolved in many organic solvents, such as ethanol acetone ether and benzene.

Structure:

The molecular structures of Benzidine contain two benzene rings. This gives the molecule a planar structure and polarity. It is white or pale yellow in color. The molecular structure of Benzidine contains many aromatic bonds, including non-polar CH bonds, with high bond energies. This results in a higher melting point and boiling point.

The benzene rings and nitrogen atoms in the molecule are stable, so Benzidine has a high level of stability. The compound also has some UV absorption and fluorescent properties that can be used to prepare fluorescent indicators and optical material.

Chemical property:

White or slightly reddish crystalline powder. The melting point is 125, the boiling point is 400 (98.7kPa), and relative density of 1.250 (20/4). It dissolves easily in boiling ethanol, dilute hydrochloric acids, and acetic acid. The color darkens with air and light.

In industry, sulfates and Benzidine chloride salts are used as analytical reagents. Benzidine acetate crystals are white or almost white and are soluble in acetic, hydrochloric, and water. It is used to indicate [36341-27-2]. Benzidine hydrochloride [531-85-1].

Benzidine sulfate, also known as benzidine sulfate, is a white powdery crystal or small flake-like crystals that are soluble only in ether. It is very slightly soluble when mixed with water, dilute acids, and alcohol.

Production Method:

The hydrogenated azobenzene is produced by reducing the nitrobenzene. It is then rearranged. In industrial production, Benzidine hydrochloride is used to re-arrange hydrogenated azobenzene.

Product Images & Packaging

Benzidine
Benzidine
Benzidine

Product Parameters

Benzidine Chemical Properties
Melting point 127-128 °C
Boiling point 402°C
density 1.25
vapor pressure Based on the specific vapor density value of 6.36 (Sims et al., 1988), the vapor pressure wascalculated to be 0.83 at 20 °C.
refractive index 1.6266 (estimate)
Fp 11 °C
storage temp. 2-8°C
solubility Soluble in ethanol (U.S. EPA, 1985) and ether (1 g/50 mL) (Windholz et al., 1983)
pka4.66(at 30℃)
color Grayish-yellow, crystalline powder; white or sltlyreddish crystals, powder
Water Solubility Sparingly soluble. <0.1 g/100 mL at 22 ºC
Merck 13,1077
BRN 742770

The application of Benzidine

History and Use of Benzidine

Benzidine is also known as 3,3′-diaminobenzidine. The most notable characteristic of Benzidine is its high carcinogenicity. Long-term exposure increases the risk of occupational diseases like bladder cancer and urinary cancer.

It was used widely in many industrial fields before the middle of the 20th century due to its excellent chemical properties.

1. Dye Industry: The most important historical uses

Benzidine was used in this area for many years. Benzidine is not a dye but a very important dye intermediate.

Mechanism of action: The two benzidine amino groups (- NH2) in its molecular structure enable it to couple up with diazo components and generate a series brightly colored, colorfast dyes called “Benzidine dyes”.

Features and benefits:

Dyes are available in a wide range of colors, from yellow to orange, brown, black and blue.

Direct dyes are easy to use: They have a good affinity for cellulose fibers and can be applied without mordants. The cost is low and the process is easy.

The fabric is a deep, rich color after dyeing.

Uses: Benzidine dyes are widely used for dyeing cotton textiles and leather. There were 200-300 different types of Benzidine Dyes available at its peak.

Since the 1970s and 1960s, when its carcinogenicity was established, many countries have begun to prohibit the sale and production of dyes and benzidine. Our country has also prohibited Benzidine and actively promoted alternatives.

2. Chemical testing and qualitative analysis

Benzidine was also used as a chemical detection reagent in the past, most notably for the “Benzidine Reaction”.

Blood test: In the presence of hydrogen-peroxide in the blood, hemoglobin can catalyze benzidine. This results in an oxidation and formation of quinones like blue products.

The fecal blood test is widely used for medical purposes and criminal investigations.

Benzidine has been eliminated as a detection agent due to its high carcinogenicity. Today, the forensics field uses safer alternatives, such as tetramethyl-Benzidine. It has similar principles, but is much less toxic. Medical occult tests for blood have also adopted more safe methods.

Benzidine 's Procurement Guide

Procurement Guidelines
1. Sample Policy
We can provide a 2-3g free trial package (shipping fee required)

2. Batch procurement
Packaging: 25kg/bag; 220kg/barrel; Special packaging according to your needs
MOQ:1kg

3. Customized services
Concentration customization (90% -99%)
Paeonol’s outsourcing services

Paeonol

FAQ

Yes, we have our own factory called ” ZhiShang Industry Group “

Yes, we have GMP certificate for some products, and we can provide DMF as well.

 -Quality you require, eg. Assay, Purity, or single impurity

-Quantity you need

-Standard you want, such as USP, EP, JP etc.

Escrow and T/T in advance are highly recommended. We can accept Western Union, Money Gram and Paypal as well.

For sample(less than 1kg), in about 3 working days after payment; for larger orders (more than 1kg), in about 7 working days after payment. 

For samples, we will send by TNT/DHL/FEDEX/UPS express, usually it takes about 3-5 day.

Related References

Manufacturer of Benzidine

Company Info

Zhishang Bio company in China that exports chemicals, Cosmetic raw materials, and Intermediates for over 70 countries now.
 
And a range of 50,000 products with the best quality and competitive price to meet your different purchasing needs.
 
The company integrates research and development, production, and trade, with a modern production base, advanced testing equipment, and an experienced technical team to ensure that products reach industry-leading levels in purity, stability, and environmental friendliness.

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