
PRODUCT

Zhishang Bio Benzidine CAS 92-87-5
CAS:92-87-5 | C12H12N2 |MW:184.24 | EINECS NO:202-199-1
Payment: L/C,T/T,D/P,Paypal,Money Gram,Western Union
Incoterm: FOB,CFR,CIF,EXW,FCA,CPT,CIP
Transporta: Ocean, Land,Air, DHL,TNT
Port: Shanghai Port, Qingdao Port
Description
Benzidine is a powdery white or light-red crystalline powder when it’s at room temperature. It is alkaline and has a low solubility with water. However, it can be dissolved in many organic solvents, such as ethanol acetone ether and benzene.
Structure:
The molecular structures of Benzidine contain two benzene rings. This gives the molecule a planar structure and polarity. It is white or pale yellow in color. The molecular structure of Benzidine contains many aromatic bonds, including non-polar CH bonds, with high bond energies. This results in a higher melting point and boiling point.
The benzene rings and nitrogen atoms in the molecule are stable, so Benzidine has a high level of stability. The compound also has some UV absorption and fluorescent properties that can be used to prepare fluorescent indicators and optical material.
Chemical property:
White or slightly reddish crystalline powder. The melting point is 125, the boiling point is 400 (98.7kPa), and relative density of 1.250 (20/4). It dissolves easily in boiling ethanol, dilute hydrochloric acids, and acetic acid. The color darkens with air and light.
In industry, sulfates and Benzidine chloride salts are used as analytical reagents. Benzidine acetate crystals are white or almost white and are soluble in acetic, hydrochloric, and water. It is used to indicate [36341-27-2]. Benzidine hydrochloride [531-85-1].
Benzidine sulfate, also known as benzidine sulfate, is a white powdery crystal or small flake-like crystals that are soluble only in ether. It is very slightly soluble when mixed with water, dilute acids, and alcohol.
Production Method:
The hydrogenated azobenzene is produced by reducing the nitrobenzene. It is then rearranged. In industrial production, Benzidine hydrochloride is used to re-arrange hydrogenated azobenzene.
Product Images & Packaging



Product Parameters
| Benzidine Chemical Properties |
| Melting point | 127-128 °C |
| Boiling point | 402°C |
| density | 1.25 |
| vapor pressure | Based on the specific vapor density value of 6.36 (Sims et al., 1988), the vapor pressure wascalculated to be 0.83 at 20 °C. |
| refractive index | 1.6266 (estimate) |
| Fp | 11 °C |
| storage temp. | 2-8°C |
| solubility | Soluble in ethanol (U.S. EPA, 1985) and ether (1 g/50 mL) (Windholz et al., 1983) |
| pka | 4.66(at 30℃) |
| color | Grayish-yellow, crystalline powder; white or sltlyreddish crystals, powder |
| Water Solubility | Sparingly soluble. <0.1 g/100 mL at 22 ºC |
| Merck | 13,1077 |
| BRN | 742770 |
The application of Benzidine
History and Use of Benzidine
Benzidine is also known as 3,3′-diaminobenzidine. The most notable characteristic of Benzidine is its high carcinogenicity. Long-term exposure increases the risk of occupational diseases like bladder cancer and urinary cancer.
It was used widely in many industrial fields before the middle of the 20th century due to its excellent chemical properties.
1. Dye Industry: The most important historical uses
Benzidine was used in this area for many years. Benzidine is not a dye but a very important dye intermediate.
Mechanism of action: The two benzidine amino groups (- NH2) in its molecular structure enable it to couple up with diazo components and generate a series brightly colored, colorfast dyes called “Benzidine dyes”.
Features and benefits:
Dyes are available in a wide range of colors, from yellow to orange, brown, black and blue.
Direct dyes are easy to use: They have a good affinity for cellulose fibers and can be applied without mordants. The cost is low and the process is easy.
The fabric is a deep, rich color after dyeing.
Uses: Benzidine dyes are widely used for dyeing cotton textiles and leather. There were 200-300 different types of Benzidine Dyes available at its peak.
Since the 1970s and 1960s, when its carcinogenicity was established, many countries have begun to prohibit the sale and production of dyes and benzidine. Our country has also prohibited Benzidine and actively promoted alternatives.
2. Chemical testing and qualitative analysis
Benzidine was also used as a chemical detection reagent in the past, most notably for the “Benzidine Reaction”.
Blood test: In the presence of hydrogen-peroxide in the blood, hemoglobin can catalyze benzidine. This results in an oxidation and formation of quinones like blue products.
The fecal blood test is widely used for medical purposes and criminal investigations.
Benzidine has been eliminated as a detection agent due to its high carcinogenicity. Today, the forensics field uses safer alternatives, such as tetramethyl-Benzidine. It has similar principles, but is much less toxic. Medical occult tests for blood have also adopted more safe methods.
Benzidine 's Procurement Guide
Procurement Guidelines
1. Sample Policy
We can provide a 2-3g free trial package (shipping fee required)
2. Batch procurement
Packaging: 25kg/bag; 220kg/barrel; Special packaging according to your needs
MOQ:1kg
3. Customized services
Concentration customization (90% -99%)
Paeonol’s outsourcing services

FAQ
Yes, we have our own factory called ” ZhiShang Industry Group “
Yes, we have GMP certificate for some products, and we can provide DMF as well.
-Quality you require, eg. Assay, Purity, or single impurity
-Quantity you need
-Standard you want, such as USP, EP, JP etc.
Escrow and T/T in advance are highly recommended. We can accept Western Union, Money Gram and Paypal as well.
For sample(less than 1kg), in about 3 working days after payment; for larger orders (more than 1kg), in about 7 working days after payment.
For samples, we will send by TNT/DHL/FEDEX/UPS express, usually it takes about 3-5 day.
Related References
Manufacturer of Benzidine
Zhishang Bio is based in Shandong, serves the whole country, faces the world, and is determined to become an excellent supplier and service provider in the chemical industry.
As a top manufacturer of cosmetic raw materials, disinfectants, flavors and fragrances in China, we are committed to producing high-quality products and have won high praise from customers all over the world.
In the next 10 years or even longer, Zhishang Bio will always adhere to the tenet of quality first and reputation first, and devote itself to providing customers with thoughtful and perfect services.
As a professional Benzidine manufacturer, Zhi shang Bio has served more than 6,000 customers around the world. Because of our high-quality products and professional services, we have won high praise from most of our customers.
Zhishang Bio is a professional enterprise engaged in the research and development, production, and sales of chemical raw materials. It has a strong supply chain system and strict quality control standards to ensure the provision of high-quality products with high purity and stability to customers.
Zhishang Bio’s core strength is its independent research and design capabilities. It has advanced production equipment, testing laboratories and can customize chemical raw materials to meet the market demands. This includes pharmaceuticals, electronic, coatings and agricultural applications.
Zhishang Bio’s supply chain management is based on long-term relationships with domestic and international suppliers of high quality to guarantee a stable supply, optimize logistic systems, and achieve efficient distribution. This helps reduce the cost of customer purchases.
We adhere to international environmental standards and we also adhere to the concept that environmental protection and safety production are important. All production processes must comply with these standards in order to guarantee that our products will be green and sustainable.
With a professional technical team and comprehensive after-sales service, Zhishang Bio can provide customers with precise technical support, solve application problems, and help customers enhance product competitiveness.
We are always customer-oriented and committed to becoming a trusted chemical raw material partner.
Zhishang Biography is dedicated to using clients extensive and expert service, including chemical raw material. The customers will certainly receive hassle-free, efficient and one-stop options.
1. Custom-made Supply Solutions
Zhishang Bio provides tailored services for clients in the chemical basic material sector, including special bit dimension, solvent residue control, stability optimizations and more. Clients can personalize their services to satisfy details requirements in industries such as drugs, electronic devices, and finishings.
2. Strict quality assurance
Zhishang Bio utilizes advanced screening equipment and stringent quality examination procedures, in addition to various other files, to guarantee that every batch of products is certified with international criteria such ISO GMP, REACH, and so on. Customers are also given with full quality records and conformity documents.
The supply chain is secure
Zhishang Bio has actually established lasting calculated collaborations with worldwide makers of top notch raw materials to make certain a secure supply, maximize the storage facility and logistics system, and assistance both small-scale examinations and large orders. It adjusted to the changing requirements of clients by responding flexibly to these changes.
4. Technical support
Zhishang Bio’s technical group can offer suggestions on product applications, formula optimization and analysis of industry patterns to aid clients fix technological troubles during production and boost item efficiency.
5. Efficient after-sales service
Zhishang Bio provides complete monitoring, reacts to client requests and delivers promptly. This will certainly make certain customer complete satisfaction.
Zhishang Biography intends to help consumers expand their service by providing the very best solutions and chemical resources.
DO YOU ACCEPT SAMPLE ORDER?
We will make samples before mass production. After the samples are approved by the department and users, we will start mass production. During the production process, we will carry out 100% inspection, and then carry out random inspection before packaging.
WHAT’S YOUR MOQ?
Our MOQ is 1kg. But usually we can also accept a smaller quantity, such as 100g, if you need it, provided that the sample fee is 100% paid.
IS THERE A DISCOUNT?
Different quantity has different discount.
HOW TO CONFIRM WHETHER THE PRODUCT QUALITY MEETS OUR NEEDS BEFORE PLACING AN ORDER?
You can consult us to get free samples of some products, you only need to pay the freight or arrange express delivery to us and get the samples. You can send us the product specifications and requirements you need, and we will manufacture products according to your requirements.
DO YOU SUPPLY PRODUCT REPORT?
Yes. We’ll give you product analysis report before shipping.
LEARN MORE ABOUT US
Shandong Look Chemical
1. For products ≤50kg, we recommend using express delivery, which is usually called DDU service (discounted, convenient).
2. For products ≤500kg, we generally recommend air freight, which is usually called FOB, CFR or CIF service (fast and efficient).
3. For products >500kg, we generally recommend shipping by sea, which is usually called FOB, CFR or CIF service (economical, safe).
4. For high-value products, please choose air or express to ensure the safety of product transportation.
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