Zhishang Bio Technology|Supplier of pharmaceutical intermediates, pesticide intermediates and cosmetics raw materials

PRODUCT

Bismuththiol

Zhishang Bio Bismuththiol CAS 1309-42-8

Payment: L/C,T/T,D/P,Paypal,Money Gram,Western Union

Incoterm: FOB,CFR,CIF,EXW,FCA,CPT,CIP

Transporta: Ocean, Land,Air, DHL,TNT

Port: Shanghai Port, Qingdao Port

Description

1. Chemical properties and classification
Bismuththiol, The chemical name is 2,5-dimercapto-1,3,4-thiadiazole, which is a sulfur-containing heterocyclic organic compound.
Its molecular formula is C ₂ H ₂ N ₂ S ∝, molecular weight is 150.25, and CAS number is 1072-71-5. In terms of chemical structure, the compound is centered around a 1,3,4-thiadiazole ring, with a thiol group (- SH) attached to each of the 2nd and 5th positions. This “double thiol+heterocyclic” structure endows it with strong coordination ability and reactivity. In chemical classification, it belongs to heterocyclic thiols and is often referred to as “Bismuththiol I” to distinguish it from its phenyl substituted derivative “Bismuththiol II”.

2. Physical characteristics and morphology
At room temperature, Bismuththiol is a white to pale yellow crystalline powder with a slight irritating odor. Its melting point is about 162 ° C (decomposition) and its density is about 1.8 g/cm ³. This compound is slightly soluble in water (with a solubility of 20 g/L at 20 ° C), easily soluble in methanol and alkaline solutions, but insoluble in non-polar organic solvents such as benzene and chloroform. In terms of storage, this compound is sensitive to air and is recommended to be sealed and stored in a cool and dry place under inert gas protection.
Low temperature conditions of 2-8 ° C are more suitable for long-term storage.

3. Industry positioning and preparation background
Bismuththiol is a multifunctional fine chemical intermediate and analytical reagent, mainly prepared by reacting hydrazine with carbon disulfide under alkaline conditions in industry. Its most prominent feature is its specific chelating ability for heavy metal ions – the sulfur atom on the thiol group can form stable colored complexes with metal ions such as bismuth, copper, and lead (red when reacting with bismuth, brown when reacting with copper, and bright yellow when reacting with lead). This characteristic makes it a classic metal ion detection reagent in analytical chemistry, and its name “Bismuththiol” comes from this. At the same time, this compound is widely used in fields such as pharmaceutical synthesis, polymer material additives, and industrial corrosion prevention due to its unique molecular structure. It should be noted that this compound is toxic to aquatic organisms and has long-term and persistent effects. When used, it should be avoided from being released into the environment.

Product Images & Packaging

Bismuththiol
Bismuththiol
Bismuththiol

Bismuththiol Parameters

Bismuththiol Chemical Properties
Melting point 162 °C (dec.)(lit.)
Boiling point 211.3±23.0 °C(Predicted)
density 1.575 (estimate)
vapor pressure 0.013Pa at 20℃
refractive index 1.5300 (estimate)
storage temp. Store below +30°C.
form Powder
pka5.66±0.20(Predicted)
color Off-white to yellow
Water Solubility 20 g/L (20 ºC)
λmax320nm(CH3CN)(lit.)
BRN 113444
InChI1S/C2H2N2S3/c5-1-3-4-2(6)7-1/h(H,3,5)(H,4,6)
InChIKeyBIGYLAKFCGVRAN-UHFFFAOYSA-N
SMILESSc1nnc(S)s1

The application of Bismuththiol

The main use of Bismuththiol
Bismuththiol plays an important role in various fields such as analysis and detection, pharmaceutical and chemical engineering, and industrial additives due to its unique bis mercapto heterocyclic structure, which combines strong coordination ability and chemical reactivity.

This is the classic and most distinctive application of Bismuththiol in the field of Analytical Chemistry.
It is used as a highly-selective analytical reagent for the qualitative and quantitative detection heavy metal ions, such as bismuth and copper. Bismuththiol reacts with bismuth to produce red complexes. Copper ions can form brown complexes. Lead ions will form bright yellow precipitates. The presence of metal ions can be determined quickly by these characteristic color changes. This compound is used in photometric analysis for the colorimetric determinations of bismuth, as well as the photometric determinations of metal elements like antimony and palladium. Its high sensitivity and selectivity make it a valuable application for fields like environmental monitor, metallurgical analyses, and geological exploration.

Pharmaceutical and fine chemical industries
Bismuththiol is an important intermediate for synthesizing various bioactive molecules in the fields of medicine and fine chemicals. The thiadiazole ring structure is the core skeleton of many antibacterial, antifungal, and antiviral drug molecules. By further modifying its thiol functional group (such as alkylation, acylation), derivatives with different pharmacological activities can be prepared. In addition, Bismuththiol and its derivatives can also be used as catalyst ligands or reaction intermediates in organic synthesis, participating in the construction of complex sulfur-containing heterocyclic compounds. Although the specific listed drug information involves trade secrets, the widespread application of this compound in the pharmaceutical intermediate market fully demonstrates its core position.


Industrial additives and functional materials field
Bismuththiol plays an important role as an industrial additive in the fields of polymer materials and petrochemicals. It is widely used as a metal passivator in lubricating oil and engine oil, which can form stable complexes with metal ions such as copper and iron that have catalytic oxidation effects in the oil, passivating their catalytic activity, thereby inhibiting oil oxidation and deterioration, and extending the service life of lubricating oil. At the same time, it is also used as an antioxidant and corrosion inhibitor to protect metal components from corrosion. In the plastic and rubber industries, Bismuthhiol can be used as an anti-aging agent for polymer materials to improve their heat and oxidation stability.
In addition, it can also be used for the production of photographic developing chemicals, flame retardants, and fuel additives. There are research reports that there have been cases of occupational allergic contact dermatitis in Bismuththiol’s production factory, reminding relevant practitioners to pay attention to protection.

The use of Bismuththiol deeply reflects the core value of sulfur-containing heterocyclic compounds in interdisciplinary applications. It is not only a “chromogenic probe” for identifying heavy metal ions in analytical laboratories, but also a “pharmaceutical cornerstone” for synthesizing complex drug molecules, and an “industrial guardian” for protecting engine oils and metal equipment.
This structurally simple yet functionally diverse compound continues to play an indispensable role in various stages such as scientific exploration, pharmaceutical research and development, and industrial manufacturing.

Bismuththiol 's Procurement Guide

Procurement Guidelines
1. Sample Policy
We can provide a 2-3g free trial package (shipping fee required)

2. Batch procurement
Packaging: 25kg/bag; 220kg/barrel; Special packaging according to your needs
MOQ:1kg

3. Customized services
Concentration customization (90% -99%)
Paeonol’s outsourcing services

Paeonol

FAQ

The color reaction or precipitation can be used to detect bismuth, copper (brown), antimony (red), and lead (yellow).

It protects gears and bearings from heavy loads, while also inhibiting corrosion and passivating copper.

We supply >=99.0% purity industrial/analytical grade DMTD with low moisture and heavy metals.

Escrow and T/T in advance are highly recommended. We can accept Western Union, Money Gram and Paypal as well.

Related References

Manufacturer of Bismuththiol

Company Info

Zhishang Bio company in China that exports chemicals, Cosmetic raw materials, and Intermediates for over 70 countries now.
 
And a range of 50,000 products with the best quality and competitive price to meet your different purchasing needs.
 
The company integrates research and development, production, and trade, with a modern production base, advanced testing equipment, and an experienced technical team to ensure that products reach industry-leading levels in purity, stability, and environmental friendliness.

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